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000862706 1001_ $$0P:(DE-Juel1)129878$$aKulikovsky, Andrei$$b0$$eCorresponding author
000862706 245__ $$aThe effect of Nafion film on the cathode catalyst layer performance in a low–Pt PEM fuel cell
000862706 260__ $$aAmsterdam [u.a.]$$bElsevier Science$$c2019
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000862706 520__ $$aA single–pore model for performance of the cathode catalyst layer (CCL) in a PEM fuel cell is developed. The model takes into account oxygen transport though the CCL depth and through the thin Nafion film, separating the pore from Pt/C species. Analytical solution to model equations reveals the limiting current density $j^{lim}_{N}$ due to oxygen transport through the Nafion film. Further, $j^{lim}_{N}$ linearly depends of the CCL thickness, i.e., the thinner the CCL, the lower $j^{lim}_{N}$. This result may explain unexpected lowering of low–Pt loaded catalyst layers performance, which has been widely discussing in literature.
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