Journal Article FZJ-2019-03511

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Growth of layered Lu2Fe3O7 and Lu3Fe4O10 single crystals exhibiting long-range charge order via the optical floating-zone method

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2019
Elsevier Amsterdam [u.a.]

Journal of crystal growth 521, 50 - 54 () [10.1016/j.jcrysgro.2019.06.003]

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Abstract: We report the controlled growth of single crystals of intercalated layered (n = 1,2) with different oxygen stoichiometries . For the first time crystals sufficiently stoichiometric to exhibit superstructure reflections in X-ray diffraction attributable to charge ordering were obtained. The estimated correlation lengths tend to be smaller than for not intercalated LuFe2O4. For Lu2Fe3O7, two different superstructures were observed, one an incommensurate zigzag pattern similar to previous observations by electron diffraction, the other an apparently commensurate pattern with () propagation. Implications for the possible charge order in the bilayers are discussed. Magnetization measurements suggest reduced magnetic correlations and the absence of an antiferromagnetic phase.

Classification:

Contributing Institute(s):
  1. Streumethoden (JCNS-2)
  2. Streumethoden (PGI-4)
  3. JARA-FIT (JARA-FIT)
Research Program(s):
  1. 144 - Controlling Collective States (POF3-144) (POF3-144)
  2. 524 - Controlling Collective States (POF3-524) (POF3-524)
  3. 6212 - Quantum Condensed Matter: Magnetism, Superconductivity (POF3-621) (POF3-621)
  4. 6213 - Materials and Processes for Energy and Transport Technologies (POF3-621) (POF3-621)
  5. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)

Appears in the scientific report 2019
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 Record created 2019-06-25, last modified 2025-01-29