Home > Publications database > An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical |
Journal Article | FZJ-2020-02104 |
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2020
RSC
London
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Please use a persistent id in citations: http://hdl.handle.net/2128/25264 doi:10.1039/C9NJ04354C
Abstract: Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl2 with Ag[C5(CN)4(NH2)] and recrystallization in MeOH, performed in sunlight. The radical was characterized by X-ray diffraction, EPR and UV Vis spectroscopy as well as by cyclovoltammetry and DFT calculations.
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