Journal Article FZJ-2020-02104

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An aminotetracyanocyclopentadienide system: light-induced formation of a thermally stable cyclopentadienyl radical

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2020
RSC London

New journal of chemistry 44(1), 72 - 78 () [10.1039/C9NJ04354C]

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Abstract: Crystals of the aminotetracyanocyclopentadienyl radical were obtained from the reaction of CaCl2 with Ag[C5(CN)4(NH2)] and recrystallization in MeOH, performed in sunlight. The radical was characterized by X-ray diffraction, EPR and UV Vis spectroscopy as well as by cyclovoltammetry and DFT calculations.

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Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
Research Program(s):
  1. 131 - Electrochemical Storage (POF3-131) (POF3-131)

Appears in the scientific report 2020
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Medline ; Embargoed OpenAccess ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; NCBI Molecular Biology Database ; National-Konsortium ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2020-05-27, last modified 2024-07-11


Published on 2019-11-18. Available in OpenAccess from 2020-11-18.:
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