Journal Article FZJ-2020-02720

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Atomic-scale investigation of spinel LiFe5O8 thin films on SrTiO3 (001) substrates

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2020
Ed. Board, Journal of Materials Science & Technology Shenyang

Journal of materials science & technology 40, 31 - 38 () [10.1016/j.jmst.2019.08.039]

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Abstract: Microstructural properties of spinel LiFe5O8 (LFO) films grown on (001)-oriented SrTiO3 (STO) substrates have been investigated at the atomic-scale by advanced electron microscopy techniques. Two types of orientation relationship (OR) between the LFO films and the STO substrates have been determined, cube-on-cube and (111)[ 10]LFO//(111)[1 0]STO. Antiphase boundaries (APBs) and three types of twin boundaries (TBs) form within the LFO films, and the propagation of TBs and APBs results in their complex interactions. In most cases, interactions between TBs and APBs change the type of TBs and terminate the propagation of APBs since the APBs introduce a displacement vector of (a/4)〈110〉 into the TBs. In addition, the interactions between two coherent TBs are observed to generate the incoherent TB. The epitaxial strain of the LFO/STO (001) heterosystem can be released by the formation of TBs and APBs in the films and misfit dislocations at the interface. Considering that the magnetic coupling across the APBs and TBs can lead to novel physical properties, the appearance of APBs and TBs with a high density in the LFO films would affect the magnetic properties of the films.

Classification:

Contributing Institute(s):
  1. Physik Nanoskaliger Systeme (ER-C-1)
Research Program(s):
  1. 143 - Controlling Configuration-Based Phenomena (POF3-143) (POF3-143)

Appears in the scientific report 2020
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Medline ; Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 ; Embargoed OpenAccess ; Allianz-Lizenz / DFG ; Clarivate Analytics Master Journal List ; Current Contents - Electronics and Telecommunications Collection ; Current Contents - Engineering, Computing and Technology ; Essential Science Indicators ; IF >= 5 ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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Open Access

 Datensatz erzeugt am 2020-08-04, letzte Änderung am 2021-01-30


Published on 2019-11-05. Available in OpenAccess from 2020-11-05.:
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