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@ARTICLE{Zeng:890011,
author = {Zeng, Fanlin and Malzbender, Jürgen and Baumann, Stefan
and Zhou, Wenyu and Ziegner, Mirko and Nijmeijer, Arian and
Guillon, Olivier and Schwaiger, Ruth and Meulenberg, Wilhelm
Albert},
title = {{M}echanical reliability of {C}e 0.8 {G}d 0.2 {O} 2− δ
‐{F}e{C}o 2 {O} 4 dual phase membranes synthesized by
one‐step solid‐state reaction},
journal = {Journal of the American Ceramic Society},
volume = {104},
number = {4},
issn = {1551-2916},
address = {Westerville, Ohio},
publisher = {Soc.},
reportid = {FZJ-2021-00605},
pages = {1814-1830},
year = {2020},
abstract = {Ce0.8Gd0.2O2−δ‐FeCo2O4 composites are attractive
candidate materials for high‐purity oxygen generation
providing robust chemical stability. Aiming for future
industrial applications, a feasible solid‐state reaction
process with one thermal processing step was used to
synthesize 50 $wt\%$ Ce0.8Gd0.2O2−δ:50 $wt\%$ FeCo2O4 and
85 $wt\%$ Ce0.8Gd0.2O2−δ:15 $wt\%$ FeCo2O4 composites.
Mechanical reliabilities of the sintered membranes were
assessed based on the characterized mechanical properties
and subcritical crack growth behavior. In general, the
fracture strengths of as‐sintered membranes were reduced
by tensile residual stresses and microcracks. In particular,
the enhanced subcritical crack growth behavior, which leads
to limited stress tolerance and high failure probability
after a 10‐year operation, was evaluated in more detail.
Further materials and processing improvements are needed to
eliminate the tensile stress and microcracks to warrant a
long‐term reliable operation of the composites.},
cin = {IEK-1 / IEK-2 / JARA-ENERGY},
ddc = {660},
cid = {I:(DE-Juel1)IEK-1-20101013 / I:(DE-Juel1)IEK-2-20101013 /
$I:(DE-82)080011_20140620$},
pnm = {113 - Methods and Concepts for Material Development
(POF3-113)},
pid = {G:(DE-HGF)POF3-113},
typ = {PUB:(DE-HGF)16},
UT = {WOS:000595824300001},
doi = {10.1111/jace.17583},
url = {https://juser.fz-juelich.de/record/890011},
}