Journal Article FZJ-2021-02139

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Precipitation behavior in G-phase strengthened ferritic stainless steels

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2021
Elsevier Science Amsterdam [u.a.]

Acta materialia 205, 116542 - () [10.1016/j.actamat.2020.116542]

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Abstract: A series of G-phase strengthened ferritic stainless steels Fe-20Cr-3Ni-3Si-X (X = 2Mn, 1Mn-2Ti, 1Mn-2Nb and 1Mn-2Ta) are characterized after aging using experimental (microhardness, TEM and APT) and theoretical (DFT) techniques. The results indicate that the Ni16Mn6Si7 G-phase shows sluggish precipitation during aging treatment. This was attributed to the small difference in the enthalpy of formation between the Ni16Mn6Si7 G- and BCC phase and the requirement of high Ni:Fe ratio. A superfine Ni16Ti6Si7 G-phase was found to precipitate as a core accompanied with an “envelope” of Fe2TiSi-L21 Heusler phase during early aging (≤24 h) in the Ti containing alloy. This morphology is predicted to occur due to early Ni clustering in ferrite and a negative Ni concentration gradient away from the cluster that favors Fe2TiSi formation. The G-phases show only particle coarsening without obvious chemical composition evolution for further aging up to 96 h. A prominent hardness increase of 100-275 HV was also observed during aging. These findings provide valuable insight into methods for precipitating low lattice mismatch silicide phases for the development of future high strength steels.

Keyword(s): Materials Science (2nd)

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Contributing Institute(s):
  1. Analytik (ZEA-3)
  2. Werkstoffstruktur und -eigenschaften (IEK-2)
Research Program(s):
  1. 899 - ohne Topic (POF4-899) (POF4-899)

Appears in the scientific report 2021
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Medline ; Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 ; Embargoed OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2021-05-11, last modified 2024-07-11


Published on 2020-12-08. Available in OpenAccess from 2021-12-08.:
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