Journal Article

FZJ-2021-03246

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png An artificial ruthenium-containing β-barrel protein for alkene–alkyne coupling reaction

Thiel, A. ; Sauer, D. F. ; Markel, U. ; Mertens, S.RWTH* ; Polen, T.FZJ* ; Schwaneberg, U. ; Okuda, J. (Corresponding author)

2021
Royal Society of Chemistry Cambridge

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Please use a persistent id in citations: http://hdl.handle.net/2128/28581  doi:10.1039/D1OB00279A

Abstract: A modified Cp*Ru complex, equipped with a maleimide group, was covalently attached to a cysteine of an engineered variant of Ferric hydroxamate uptake protein component: A (FhuA). This synthetic metalloprotein catalyzed the intermolecular alkene–alkyne coupling of 3-butenol with 5-hexynenitrile. When compared with the protein-free Cp*Ru catalyst, the biohybrid catalyst produced the linear product with higher regioselectivity.

Note: Biotechnolgie 1

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Contributing Institute(s):

1. Biotechnologie (IBG-1)

Research Program(s):

1. 2172 - Utilization of renewable carbon and energy sources and engineering of ecosystem functions (POF4-217) (POF4-217)

Appears in the scientific report 2021

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Database coverage:
; ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Life Sciences ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF < 5 ; Index Chemicus ; JCR ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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