Journal Article FZJ-2021-04868

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png
How alkaline compounds control atmospheric aerosol particle acidity

 ;  ;  ;

2021
EGU Katlenburg-Lindau

Atmospheric chemistry and physics 21(19), 14983 - 15001 () [10.5194/acp-21-14983-2021]

This record in other databases:    

Please use a persistent id in citations:   doi:

Abstract: The acidity of atmospheric particulate matter regulates its mass, composition, and toxicity and has important consequences for public health, ecosystems and climate. Despite these broad impacts, the global distribution and evolution of aerosol particle acidity are unknown. We used the comprehensive atmospheric multiphase chemistry–climate model EMAC (ECHAM5/MESSy Atmospheric Chemistry) to investigate the main factors that control aerosol particle acidity and uncovered remarkable variability and unexpected trends during the past 50 years in different parts of the world. Aerosol particle acidity decreased strongly over Europe and North America during the past decades while at the same time it increased over Asia. Our simulations revealed that these particle acidity trends are strongly related to changes in the phase partitioning of nitric acid, production of sulfate in aqueous aerosols, and the aerosol hygroscopicity. It is remarkable that the aerosol hygroscopicity (κ) has increased in many regions following the particle pH. Overall, we find that alkaline compounds, notably ammonium and to a lesser extent crustal cations, regulate the particle pH on a global scale. Given the importance of aerosol particles for the atmospheric energy budget, cloud formation, pollutant deposition, and public health, alkaline species hold the key to control strategies for air quality and climate change.

Classification:

Contributing Institute(s):
  1. Troposphäre (IEK-8)
Research Program(s):
  1. 2111 - Air Quality (POF4-211) (POF4-211)

Appears in the scientific report 2021
Database coverage:
Medline ; Creative Commons Attribution CC BY 4.0 ; DOAJ ; OpenAccess ; Article Processing Charges ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Essential Science Indicators ; Fees ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
Click to display QR Code for this record

The record appears in these collections:
Document types > Articles > Journal Article
Institute Collections > ICE > ICE-3
Workflow collections > Public records
IEK > IEK-8
Publications database
Open Access

 Record created 2021-12-02, last modified 2024-07-12


OpenAccess:
Download fulltext PDF
External link:
Download fulltextFulltext by OpenAccess repository
Rate this document:

Rate this document:
1
2
3
 
(Not yet reviewed)