Journal Article

FZJ-2021-05727

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Chemical Tomography in a Fresh Wildland Fire Plume: A Large Eddy Simulation (LES) Study

Wang, S. (Corresponding author) ; Coggon, M. M. ; Gkatzelis, G.FZJ* ; Warneke, C. ; Bourgeois, I. ; Ryerson, T. ; Peischl, J. ; Veres, P. R. ; Neuman, J. A. ; Hair, J. ; Shingler, T. ; Fenn, M. ; Diskin, G. ; Huey, L. G. ; Lee, Y. R. ; Apel, E. C. ; Hornbrook, R. S. ; Hills, A. J. ; Hall, S. R. ; Ullmann, K. ; Bela, M. M. ; Trainer, M. K. ; Kumar, R. ; Orlando, J. J. ; Flocke, F. M. ; Emmons, L. K.

2021
Wiley Hoboken, NJ

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Please use a persistent id in citations: http://hdl.handle.net/2128/29883  doi:10.1029/2021JD035203

Abstract: Wildland fires involve complicated processes that are challenging to represent in chemical transport models. Recent airborne measurements reveal remarkable chemical tomography in fresh wildland fire plumes, which remain yet to be fully explored using models. Here, we present a high-resolution large eddy simulation model coupled to chemistry to study the chemical evolution in fresh wildland fire plume. The model is configured for a large fire heavily sampled during the Fire Influence on Regional to Global Environments and Air Quality field campaign, and a variety of airborne measurements are used to evaluate the chemical heterogeneity revealed by the model. We show that the model captures the observed cross-transect variations of a number of compounds quite well, including ozone (O3), nitrous acid (HONO), and peroxyacetyl nitrate. The combined observational and modeling results suggest that the top and edges of fresh plume drive the photochemistry, while dark chemistry is also present but in the lower part of the plume. The model spatial resolution is shown to be very important as it may shift the chemical regime, leading to biases in O3 and NOx chemistry. Based on findings in this work, we speculate that the impact of small fires on air quality may be largely underestimated in models with coarse spatial resolutions.

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Contributing Institute(s):

1. Troposphäre (IEK-8)

Research Program(s):

1. 2111 - Air Quality (POF4-211) (POF4-211)

Appears in the scientific report 2021

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Database coverage:
; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Wiley ; Essential Science Indicators ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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