Journal Article

FZJ-2023-01763

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Polyelectrolyte Complexes from Oppositely Charged Filamentous Viruses

Anop, H. ; Buitenhuis, J. (Corresponding author)FZJ*

2023
ACS Publ. Washington, DC

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Please use a persistent id in citations: http://hdl.handle.net/2128/34350  doi:10.1021/acs.langmuir.2c02790

Abstract: Here, we present an explorative study on a new type of polyelectrolyte complex made from chemically modified filamentous fd viruses. The fd virus is a semiflexible rod-shaped bacteriophage with a length of 880 nm and a diameter of 6.6 nm, which has been widely used as a well-defined model system of colloidal rods to investigate phase, flow, and other behavior. Here, chemically modified viruses have been prepared to obtain two types with opposite electrical charges in addition to a steric stabilization layer by poly(ethylene glycol) (PEG) grafting. The complex formation of stoichiometric mixtures of these oppositely charged viruses is studied as a function of virus and salt concentration. Furthermore, static light scattering measurements show a varying, strong increase in scattering intensity in some samples without visual macroscopic complex formation. Finally, the results of the complex formation are rationalized by comparing to model calculations on the pair interaction potential between oppositely charged viruses.

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Contributing Institute(s):

1. Biomakromolekulare Systeme und Prozesse (IBI-4)

Research Program(s):

1. 5241 - Molecular Information Processing in Cellular Systems (POF4-524) (POF4-524)

Appears in the scientific report 2023

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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