Journal Article

FZJ-2023-02107

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Gauging the importance of structural parameters for hyperfine coupling constants in organic radicals

Szczuka, C. (Corresponding author)FZJ* ; Eichel, R.-A.FZJ*RWTH* ; Granwehr, J.FZJ*RWTH*

2023
RSC Publishing London

This record in other databases:      

Please use a persistent id in citations: doi:10.1039/D3RA02476H  doi:10.34734/FZJ-2023-02107

Abstract: The identification of fundamental relationships between atomic configuration and electronic structure typically requires experimental empiricism or systematic theoretical studies. Here, we provide an alternative statistical approach to gauge the importance of structure parameters, i.e., bond lengths, bond angles, and dihedral angles, for hyperfine coupling constants in organic radicals. Hyperfine coupling constants describe electron–nuclear interactions defined by the electronic structure and are experimentally measurable, for example, by electron paramagnetic resonance spectroscopy. Importance quantifiers are computed with the machine learning algorithm neighborhood components analysis using molecular dynamics trajectory snapshots. Atomic–electronic structure relationships are visualized in matrices correlating structure parameters with coupling constants of all magnetic nuclei. Qualitatively, the results reproduce common hyperfine coupling models. Tools to use the presented procedure for other radicals/paramagnetic species or other atomic structure-dependent parameters are provided.

---

Contributing Institute(s):

1. Grundlagen der Elektrochemie (IEK-9)

Research Program(s):

1. 1223 - Batteries in Application (POF4-122) (POF4-122)

Appears in the scientific report 2023

---

Database coverage:
; ; ; ; Article Processing Charges ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Essential Science Indicators ; Fees ; IF < 5 ; JCR ; National-Konsortium ; PubMed Central ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

---