Journal Article

FZJ-2025-03550

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Magnetoelastic Dynamics of the Spin Jahn-Teller Transition in CoTi 2 O 5

Guratinder, K. ; Johnson, R. D. ; Prabhakaran, D. ; Taylor, R. A. ; Lang, F. ; Blundell, S. J. ; Taran, L. S. ; Streltsov, S. V. ; Williams, T. J. ; Giblin, S. R. ; Fennell, T. ; Schmalzl, K.FZJ* ; Stock, C.

2025
APS College Park, Md.

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Please use a persistent id in citations: doi:10.1103/sr9s-ll1y  doi:10.34734/FZJ-2025-03550

Abstract: CoTi2⁢O5has the paradox that low temperature static magnetic order is incompatible with the crystal structure owing to a mirror plane that exactly frustrates magnetic interactions. Despite no observable structural distortion with diffraction, CoTi2⁢O5does magnetically order below 𝑇𝑁∼25  Kwith the breaking of spin ground state degeneracy proposed to be a realization of the spin Jahn-Teller effect in analogy to the celebrated orbital Jahn-Teller transition. We apply neutron and Raman spectroscopy to study the dynamics of this transition in CoTi2⁢O5. We find anomalous acoustics associated with a symmetry breaking strain that characterizes the spin Jahn-Teller transition. Crucially, the energy of this phonon coincides with the energy scale of the magnetic excitations, and has the same symmetry of an optic mode, observed with Raman spectroscopy, which atypically softens in energy with decreasing temperature. Taken together, we propose that the energetics of the spin Jahn-Teller effect in CoTi2⁢O5are related to cooperative magnetoelastic fluctuations as opposed to conventional soft critical dynamics which typically drive large measurable static displacements.

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Contributing Institute(s):

1. Streumethoden (JCNS-2)
2. JARA-FIT (JARA-FIT)
3. JCNS-ILL (JCNS-ILL)

Research Program(s):

1. 632 - Materials – Quantum, Complex and Functional Materials (POF4-632) (POF4-632)
2. 6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4) (POF4-6G4)

Appears in the scientific report 2025

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Database coverage:
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