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| Hauptseite > Publikationsdatenbank > Effects of A- and B-site (co-)acceptor doping on the structure and proton conductivity of LaNbO4 |
| Hauptseite > Publikationsdatenbank > Effects of A- and B-site (co-)acceptor doping on the structure and proton conductivity of LaNbO4 |
| Journal Article | PreJuSER-11309 |
; ; ; ;
2012
Elsevier Science
Amsterdam [u.a.]
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Please use a persistent id in citations: doi:10.1016/j.ssi.2011.06.012
Abstract: B-site and A- and B-site co-doped lanthanum niobates, La(1-x)DA(x)Nb(1-y)DB(y)O(4-delta), where D-A stands for Ca or Ba and D-B for Ga, Ge or In (x = 0 or 0.01; y = 0.01), have been synthesized via the solid-state route. Essentially single-phase materials were obtained after 10 h at 1500 degrees C with monoclinic Fergusonite structure at room temperature. The unit cell volume increases slightly with the presence of the acceptor. The electrical conductivity of the materials, characterized as a function of the temperature from 300 degrees C to 900 degrees C under wet reducing conditions with AC impedance spectroscopy, was dominated by protons. The maximum conductivity of 4.1 . 10(-4) S . cm(-1) at 900 degrees C was obtained for La0.99Ca0.01Nb0.99Ga0.01O4-delta, which is a factor of similar to 2.5 lower than the highest conductivity reported for the A-site Ca-doped LaNbO4. Based on a semi-quantitative evaluation it was shown that the hydration of the B-site and A- and B-site co-doped LaNbO4, is slightly more exothermic and that the proton mobility has higher activation enthalpies than Ca-doped LaNbO4. This is accounted for by a stronger association between the acceptor and the proton for B-site than for A-site doping. (c) 2011 Elsevier B.V. All rights reserved.
Keyword(s): J ; Proton-conducting ceramic materials (auto) ; Rare earth ortho-niobates (auto) ; Acceptor-doped lanthanum niobate (auto)
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