Journal Article PreJuSER-21323

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Drift velocity in non-isothermal inhomogeneous systems

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2012
American Institute of Physics Melville, NY

The journal of chemical physics 136, 204508 () [10.1063/1.4723685]

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Abstract: Drift velocity and driving force are not directly proportional in the case of inhomogeneous suspensions, where a space dependent mobility induces an additional contribution to the drift velocity. Similarly, particle flux and drift velocity are related not only by the gradient of density but also by an additional contribution given by the gradient of the self-diffusion coefficient. We provide quantitative support to this scenario in a non-equilibrium system by means of computer simulations with a temperature gradient. Moreover, our simulation results demonstrate that the temperature gradient-induced mass transport coefficient, namely thermal diffusion coefficient, is not directly proportional to the drift velocity so that the well-accepted relation of proportionality is just an approximation.

Keyword(s): Algorithms (MeSH) ; Computer Simulation (MeSH) ; Diffusion (MeSH) ; Models, Chemical (MeSH) ; Suspensions (MeSH) ; Thermodynamics (MeSH) ; Suspensions ; J


Note: Record converted from VDB: 12.11.2012

Contributing Institute(s):
  1. Theorie der weichen Materie und Biophysik (ICS-2)
Research Program(s):
  1. BioSoft: Makromolekulare Systeme und biologische Informationsverarbeitung (P45)

Appears in the scientific report 2012
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Medline ; OpenAccess by Allianz-OA ; OpenAccess ; Allianz-Lizenz / DFG ; Current Contents - Social and Behavioral Sciences ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Datensatz erzeugt am 2012-11-13, letzte Änderung am 2024-06-10


Published under German "Allianz" Licensing conditions on 2012-05-31. Available in OpenAccess from 2012-05-31:
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