Journal Article PreJuSER-22290

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Measurement of the Binding Energies of the Organic-Metal Perylene-Teracarboxylic-Dianhydride/Au(111) Bonds by Molecular Manipulation Using an Atomic Force Microscope

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2012
APS College Park, Md.

Physical review letters 109, 076102 () [10.1103/PhysRevLett.109.076102]

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Abstract: Based on single molecule manipulation experiments in a combined scanning tunneling microscope/frequency modulated atomic force microscope, we quantify the individual binding energy contributions to an organic-metal bond experimentally. The method allows the determination of contributions from, e. g., local chemical bonds, metal-molecule hybridization, and van der Waals interactions, as well as the total adsorption energy.

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Note: We gratefully acknowledge T. Lippert, N. Attig, O. Buchner, and W. Homberg (Forschungszentrum Julich) who have supported us with CPU time on JUDGE. We thank D. Park and J. Mayer from RWTH Aachen for help with the focused ion beam. R. T. thanks the Helmholtz-Gemeinschaft for financial support for his Young Investigator Research Group. This work has been supported by the Deutsche Forschungsgemeinschaft under projects TA244/5-1 and TA244/5-2.

Contributing Institute(s):
  1. Funktionale Nanostrukturen an Oberflächen (PGI-3)
  2. Jülich-Aachen Research Alliance - Fundamentals of Future Information Technology (JARA-FIT)
Research Program(s):
  1. Grundlagen für zukünftige Informationstechnologien (P42)

Appears in the scientific report 2012
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 Record created 2012-11-13, last modified 2020-04-23


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