Journal Article FZJ-2016-01446

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A Novel Sol-Gel Method for Large-Scale Production of Nanopowders: Preparation of Li $_{1.5}$ Al $_{0.5}$ Ti $_{1.5}$ (PO $_{4}$ ) $_{3}$ as an Example

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2016
Wiley-Blackwell Oxford [u.a.]

Journal of the American Ceramic Society 99(2), 410-414 () [10.1111/jace.13997]

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Abstract: Sol–gel synthesis is an extensively used method for the preparation of nanopowders. However, complicated or expensive precursors, and the necessity of using organic solvent and/or heat assistance limit the method to laboratory-scaled level. An aqueous-based sol–gel method with spontaneous sol and gel formation is developed in this study. It can be applied on a large scale to synthesize compounds with Ti4+ and PO43− as major components with low cost. Al-substituted LiTi2(PO4)3 (LATP) has been widely investigated as a promising candidate for solid electrolyte in Li-ion or Li-air batteries. Major challenges such as unsatisfactory phase purity, low sintering activity, and high production costs are faced during the fabrication of LATP. In this study, as a sample application, Li1.5Al0.5Ti1.5(PO4)3 (LATP05) is conveniently prepared on a large scale by the novel sol–gel method with high phase purity, active densification behavior and high conductivity.

Classification:

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
  2. JARA-ENERGY (JARA-ENERGY)
  3. Helmholtz-Institut Münster Ionenleiter für Energiespeicher (IEK-12)
Research Program(s):
  1. 131 - Electrochemical Storage (POF3-131) (POF3-131)

Appears in the scientific report 2016
Database coverage:
Medline ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; NationallizenzNationallizenz ; No Authors Fulltext ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Document types > Articles > Journal Article
JARA > JARA > JARA-JARA\-ENERGY
Institute Collections > IMD > IMD-2
Institute Collections > IMD > IMD-4
Workflow collections > Public records
IEK > IEK-12
IEK > IEK-1
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 Record created 2016-02-01, last modified 2024-07-12


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