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| Hauptseite > Publikationsdatenbank > Structure of interacting aggregates of silicia nanoparticles in a polymer matrix: Small-angle scattering and reverse Monte-Carlo simulations |
| Hauptseite > Publikationsdatenbank > Structure of interacting aggregates of silicia nanoparticles in a polymer matrix: Small-angle scattering and reverse Monte-Carlo simulations |
| Journal Article | PreJuSER-56808 |
; ;
2007
Royal Society of Chemistry (RSC)
Cambridge
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Please use a persistent id in citations: http://hdl.handle.net/2128/22855 doi:10.1039/b614957j
Abstract: Reinforcement of elastomers by colloidal nanoparticles is an important application where microstructure needs to be understood-and, if possible, controlled-if one wishes to tune macroscopic mechanical properties. Here, the three-dimensional structure of large aggregates of nanometric silica particles embedded in a soft polymeric matrix is determined by small angle neutron scattering. Experimentally, the crowded environment leading to strong reinforcement induces a strong interaction between aggregates, which generates a prominent interaction peak in the scattering. We propose to analyze the total signal by means of a decomposition in a classical colloidal structure factor describing aggregate interaction and an aggregate form factor determined by a reverse Monte Carlo technique. The result gives new insight to the shape of aggregates and their complex interaction in elastomers. For comparison, fractal models for aggregate scattering are also discussed.
Keyword(s): J
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