Journal Article

FZJ-2016-07385

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png [CrF(O$_{2}$C$^{t}$Bu)$_{2}$]$_{9}$: Synthesis and Characterization of a Regular Homometallic Ring with an Odd Number of Metal Centers and Electrons

Woolfson, R. J. ; Timco, G. A. ; Chiesa, A. ; Vitorica-Yrezabal, I. J. ; Tuna, F. ; Guidi, T. ; Pavarini, E.FZJ* ; Santini, P. ; Carretta, S. ; Winpenny, R. E. P. (Corresponding author)

2016
Wiley-VCH Weinheim

This record in other databases:      

Please use a persistent id in citations: http://hdl.handle.net/2128/13175  doi:10.1002/anie.201601734

Abstract: The first regular homometallic ring containing an odd number of metal centers is reported. The ring was synthesized by means of amine‐templated self‐assembly. Extensive physical characterization studies, including magnetic measurements, powder inelastic neutron scattering (INS), and DFT calculations, show that the molecule has a near perfect match to the expected behavior for a frustrated system with the lowest energy pair of S=1/2 spin states separated by only 0.1 meV (0.8 cm−1)

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Contributing Institute(s):

1. Theoretische Nanoelektronik (IAS-3)

Research Program(s):

1. 144 - Controlling Collective States (POF3-144) (POF3-144)

Appears in the scientific report 2016

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Database coverage:
; ; ; Current Contents - Life Sciences ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 10 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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