Journal Article

FZJ-2017-00335

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Modifying the Surface of a Rashba-Split Pb-Ag Alloy Using Tailored Metal-Organic Bonds

Stadtmüller, B. (Corresponding author) ; Seidel, J. ; Haag, N. ; Grad, L. ; Tusche, C.FZJ* ; van Straaten, G.FZJ* ; Franke, M.FZJ* ; Kirschner, J. ; Kumpf, C.FZJ* ; Cinchetti, M. ; Aeschlimann, M.

2016
APS College Park, Md.

This record in other databases:    

Please use a persistent id in citations: http://hdl.handle.net/2128/13429  doi:10.1103/PhysRevLett.117.096805

Abstract: Hybridization-related modifications of the first metal layer of a metal-organic interface are difficult to access experimentally and have been largely neglected so far. Here, we study the influence of specific chemical bonds (as formed by the organic molecules CuPc and PTCDA) on a Pb-Ag surface alloy. We find that delocalized van der Waals or weak chemical π-type bonds are not strong enough to alter the alloy, while localized σ-type bonds lead to a vertical displacement of the Pb surface atoms and to changes in the alloy’s surface band structure. Our results provide an exciting platform for tuning the Rashba-type spin texture of surface alloys using organic molecules.

---

Contributing Institute(s):

1. Funktionale Nanostrukturen an Oberflächen (PGI-3)

Research Program(s):

1. 143 - Controlling Configuration-Based Phenomena (POF3-143) (POF3-143)

Appears in the scientific report 2016

---

Database coverage:
; ; ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

---