Journal Article FZJ-2017-03259

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Fast Diffusion of Long Guest Rods in a Lamellar Phase of Short Host Particles

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2017
APS College Park, Md.

Physical review letters 118(17), 178002 () [10.1103/PhysRevLett.118.178002]

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Abstract: We investigate the dynamic behavior of long guest rodlike particles immersed in liquid crystallinephases formed by shorter host rods, tracking both guest and host particles by fluorescence microscopy.Counterintuitively, we evidence that long rods diffuse faster than short rods forming the one-dimensionalordered smectic-A phase. This results from the larger and noncommensurate size of the guest particles ascompared to the wavelength of the energy landscape set by the lamellar stack of liquid slabs. The long guestparticles are also shown to be still mobile in the crystalline smectic-B phase, as they generate their ownvoids in the adjacent layers.

Classification:

Contributing Institute(s):
  1. Weiche Materie (ICS-3)
Research Program(s):
  1. 551 - Functional Macromolecules and Complexes (POF3-551) (POF3-551)

Appears in the scientific report 2017
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Medline ; American Physical Society Transfer of Copyright Agreement ; OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2017-04-26, last modified 2024-06-19