Journal Article FZJ-2017-06700

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Atomic-scale structure and formation of antiphase boundaries in α-Li 0.5 Fe 2.5 O 4 thin films on MgAl 2 O 4 (001) substrates

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2017
Elsevier Science Amsterdam [u.a.]

Acta materialia 127, 178 - 184 () [10.1016/j.actamat.2017.01.022]

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Abstract: The occurrence of antiferromagnetic coupling at antiphase domain boundaries (APBs) of ferromagnetic materials holds potential applications for room-temperature spintronic devices. Here, we report formation mechanism and atomic-scale structure properties of APBs in α-Li0.5Fe2.5O4 thin films on MgAl2O4 (001) substrates investigated by means of aberration-corrected scanning transmission electron microscopy. The APBs in the α-Li0.5Fe2.5O4 films are either conservative or non-conservative. Across the APBs the oxygen sublattice in α-Li0.5Fe2.5O4 is maintained, while the stacking sequence of the cation sublattice is interrupted. The propagation of APBs is found to occur in a complex way within the ferromagnetic films, including the dissociation of APBs and the formation of kinks. Importantly, the density of APBs can be tuned by controlling the thickness of the α-Li0.5Fe2.5O4 films since the APBs bound interfacial dislocations contributing to film-substrate strain relaxation. Our results evidence that the nano-scale APBs in the α-Li0.5Fe2.5O4 films are controllable and stable, which could be promising candidates for applications in nano-spintronic devices.

Classification:

Contributing Institute(s):
  1. Physik Nanoskaliger Systeme (ER-C-1)
Research Program(s):
  1. 143 - Controlling Configuration-Based Phenomena (POF3-143) (POF3-143)

Appears in the scientific report 2017
Database coverage:
Medline ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Dokumenttypen > Aufsätze > Zeitschriftenaufsätze
Institutssammlungen > ER-C > ER-C-1
Workflowsammlungen > Öffentliche Einträge
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