Journal Article FZJ-2018-00198

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High-temperature oxidation and compressive strength of Cr2AlC MAX phase foams with controlled porosity

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2018
Wiley-Blackwell Oxford [u.a.]

Journal of the American Ceramic Society 101(2), 542 - 552 () [10.1111/jace.15224]

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Abstract: Cr2AlC foams have been processed for the first time containing low (35 vol%), intermediate (53 vol%), and high (75 vol%) content of porosity and three ranges of pore size, 90-180 μm, 180-250 μm, and 250-400 μm. Sacrificial template technique was used as the processing method, utilizing NH4HCO3 as a temporary pore former. Cr2AlC foams exhibited negligible oxidation up to 800°C and excellent response up to 1300°C due to the in-situ formation of an outer thin continuous protective layer of α-Al2O3. The in-situ α-Al2O3 protective layer covered seamlessly all the external surface of the pores, even when they present sharp angles and tight corners, reducing significantly the further oxidation of the foams. The compressive strength of the foams was 73 and 13 MPa for 53 vol% and 75 vol% porosity, respectively, which increased up to 128 and 24 MPa after their oxidation at 1200°C for 1 hour. The increase in the compressive strength after the oxidation was caused by the switch from inter- to transgranular fracture mode. According to the excellent high-temperature response, heat exchangers and catalyst supports are the potential application of these foams.

Classification:

Contributing Institute(s):
  1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
  2. JARA-ENERGY (JARA-ENERGY)
Research Program(s):
  1. 111 - Efficient and Flexible Power Plants (POF3-111) (POF3-111)
  2. 113 - Methods and Concepts for Material Development (POF3-113) (POF3-113)

Appears in the scientific report 2018
Database coverage:
Medline ; OpenAccess ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; NationallizenzNationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Open Access

 Record created 2018-01-08, last modified 2024-07-11