Journal Article

FZJ-2018-02255

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png A Detailed Post Mortem Analysis of Solid Oxide Electrolyzer Cells after Long-Term Stack Operation

Frey, C.FZJ* ; Fang, Q.FZJ* ; Sebold, D.FZJ* ; Blum, L.FZJ* ; Menzler, N. H. (Corresponding author)FZJ*

2018
Electrochemical Soc. Pennington, NJ

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Please use a persistent id in citations: http://hdl.handle.net/2128/18039  doi:10.1149/2.0961805jes

Abstract: A long-term test with a two-layer solid oxide electrolyzer stack was carried out for more than 20 000 hours. The stack was mainly operated in a furnace environment in electrolysis mode, with 50% humidification of H2 at 800°C, a current density of −0.5 Acm−2 and steam conversion rate of 50%. After ∼18 000 hours of operation in electrolysis mode, the voltage and area specific resistance degradation rates were ∼0.6%/kh and 8.2%/kh, respectively. A detailed post mortem analysis of cells including ICP-OES and microstructural analysis was conducted. Two main degradation phenomena were observed in the cells: In the fuel electrode, the depletion and agglomeration of nickel were visible. At the air electrode, demixing of the air electrode and diffusion of strontium took place. This was observed in the formation of strontium zirconate at the interface between the electrolyte and the GDC barrier layer as well as in the formation of strontium oxide and strontium chromate on top of the cells. Strontium oxide was even found in pores on top of the electrolyte.

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Contributing Institute(s):

1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)
2. Elektrochemische Verfahrenstechnik (IEK-3)

Research Program(s):

1. 135 - Fuel Cells (POF3-135) (POF3-135)
2. SOFC - Solid Oxide Fuel Cell (SOFC-20140602) (SOFC-20140602)

Appears in the scientific report 2018

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Database coverage:
; ; ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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