Journal Article FZJ-2018-05175

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Stability of near-surface ordering of bicontinuous microemulsions in external shear-fields

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2019
Elsevier Amsterdam [u.a.]

Journal of colloid and interface science 534, 31 - 36 () [10.1016/j.jcis.2018.09.014]

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Abstract: The lubrication effect of bicontinuous microemulsions describes a facilitated flow along hydrophilic planar surfaces because the fluid forms lamellar domains that can slide off along each other much better than randomly ordered domains. The applicability of this effect is based on the prerequisite of the lamellar structure not being destroyed by external shear-fields. In this paper, we demonstrate that the lamellar structure is highly stable for shear rates of up to 600 s−1 using neutron reflectivity and grazing incidence small angle neutron scattering experiments. The transition structure that consists of perforated lamellae is attacked by the flow, and the bicontinuous microemulsion comes closer to the solid interface when shear is applied. All of this verifies the stability of the lubrication effect for technical applications.

Keyword(s): Others (1st) ; Soft Condensed Matter (2nd)

Classification:

Contributing Institute(s):
  1. JCNS-FRM-II (JCNS (München) ; Jülich Centre for Neutron Science JCNS (München) ; JCNS-FRM-II)
  2. Neutronenstreuung (Neutronenstreuung ; JCNS-1)
Research Program(s):
  1. 524 - Controlling Collective States (POF3-524) (POF3-524)
  2. 6212 - Quantum Condensed Matter: Magnetism, Superconductivity (POF3-621) (POF3-621)
  3. 6G15 - FRM II / MLZ (POF3-6G15) (POF3-6G15)
  4. 6G4 - Jülich Centre for Neutron Research (JCNS) (POF3-623) (POF3-623)
Experiment(s):
  1. MARIA: Magnetic reflectometer with high incident angle (NL5N)

Appears in the scientific report 2019
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Medline ; Creative Commons Attribution CC BY 4.0 ; OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Institute Collections > JCNS > JCNS-FRM-II
Document types > Articles > Journal Article
Institute Collections > JCNS > JCNS-1
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 Record created 2018-09-05, last modified 2022-09-30