Journal Article

FZJ-2019-00689

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png One-Step Lignocellulose Fractionation by using 2,5-Furandicarboxylic Acid as a Biogenic and Recyclable Catalyst

Weidener, D. ; Klose, H.FZJ* ; Leitner, W. ; Schurr, U.FZJ* ; Usadel, B.FZJ* ; DomínguezdeMaría, P. (Corresponding author) ; Grande, P. (Corresponding author)FZJ*

2018
Wiley-VCH Weinheim

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Please use a persistent id in citations: doi:10.1002/cssc.201800653

Abstract: To develop novel biorefinery concepts, the use of bio‐based catalysts and solvents must be aligned with the principles of green chemistry. In this context, biogenic 2,5‐furandicarboxylic acid (FDCA) is a very promising yet underused molecule with high potential for application as an acid catalyst, combining feasibility and sustainability with efficient and straightforward recovery. In this study, FDCA was evaluated as a catalyst in the recently developed OrganoCat pretreatment, a biphasic lignocellulose fractionation system. The catalyst was investigated for the efficient fractionation of the three main components—lignin, cellulose and noncellulosic sugars—with particular focus on the lignin quality, on the effect on enzymatic hydrolysis of the cellulosic residue, and on the noncellulosic sugar extraction. To address recovery of FDCA from the OrganoCat system, a method was developed, leading to the recovery of >97 % of FDCA with a spectroscopic purity of >99 %, maintaining full activity in consecutive runs

Keyword(s): Chemistry (2nd) ; Industrial Application (2nd)

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Contributing Institute(s):

1. Pflanzenwissenschaften (IBG-2)

Research Program(s):

1. 582 - Plant Science (POF3-582) (POF3-582)

Appears in the scientific report 2018

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Database coverage:
; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection

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