Journal Article

FZJ-2019-03012

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Electrochemical cross-coupling of biogenic di-acids for sustainable fuel production

Holzhäuser, F. J.RWTH* ; Creusen, G. ; Moos, G.RWTH* ; Dahmen, M.FZJ* ; König, A.RWTH* ; Artz, J.RWTH* ; Palkovits, S.RWTH* ; Palkovits, R. (Corresponding author)RWTH*

2019
RSC Cambridge

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Please use a persistent id in citations: http://hdl.handle.net/2128/22824  doi:10.1039/C8GC03745K

Abstract: Direct electrocatalytic conversion of bio-derivable acids represents a promising technique for the production of value-added chemicals and tailor-made fuels from lignocellulosic biomass. In the present contribution, we report the electrochemical decarboxylation and cross-coupling of ethyl hydrogen succinate, methyl hydrogen methylsuccinate and methylhexanoic acid with isovaleric acid. The reactions were performed in aqueous solutions or methanol at ambient temperatures, following the principles of green chemistry. High conversions of the starting materials have been obtained with maximum yields between 42 and 61% towards the desired branched alkane products. Besides costly Pt electrodes also (RuxTi1−x)O2 on Ti electrodes exhibited a notable activity for cross-Kolbe electrolysis. As some of the products are insoluble in water, easy product isolation and reuse of the reaction solvent is enabled via phase separation. Several side products have been identified to evaluate the efficiency of the reaction and to elucidate the factors influencing the product selectivity. The yielded alkanes and esters were assessed with regard to their potential as fuels for internal combustion engines. While the longer alkanes constitute promising candidates for the compression–ignition engine, the smaller ester represents an interesting option for the spark-ignition engine

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Contributing Institute(s):

1. Modellierung von Energiesystemen (IEK-10)

Research Program(s):

1. 153 - Assessment of Energy Systems – Addressing Issues of Energy Efficiency and Energy Security (POF3-153) (POF3-153)

Appears in the scientific report 2019

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Database coverage:
; ; ; Allianz-Lizenz / DFG ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Web of Science Core Collection

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