| Hauptseite > Publikationsdatenbank > Facile route for reactive coating of LaCrO3 on high-chromium steels as protective layer for solid oxide fuel cell applications |
| Journal Article | FZJ-2019-05527 |
; ;
2020
Elsevier
New York, NY [u.a.]
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Please use a persistent id in citations: http://hdl.handle.net/2128/24307 doi:10.1016/j.matlet.2019.126794
Abstract: In this study, we present a facile route for the production of thin LaCrO3 layers as a protective layer on chromium-containing steels, usually applied as a dense interconnector material for solid oxide fuel cells or porous supports for metal-supported solid oxide fuel cells. The reactive sol-gel coating method is based on dip coating in aqueous lanthanum acetate/propionate mixtures and subsequent firing. LaCrO3 is formed by a reaction between lanthanum from the coating solution and chromium from the steel. The obtained layers are thin and adhere well to the sample surface. X-ray diffraction reveals the pattern of the LaCrO3 phases. Thermogravimetric measurements show the improved oxidation resistance of LaCrO3-coated steel. Because of the easy-to-apply nature of this method and the wide range of tailoring possibilities, the reactive coating route is a viable alternative to established nitrate- or alcoholate-based wet chemical coating technologies.
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