Journal Article

FZJ-2019-06540

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Dielectric properties of amorphous phase-change materials

Chen, C. ; Jost, P. ; Volker, H. ; Kaminski, M. ; Wirtssohn, M. ; Engelmann, U. ; Krüger, K. ; Schlich, F. ; Schlockermann, C. ; Lobo, R. P. S. M. ; Wuttig, M. (Corresponding author)FZJ*

2017
Inst. Woodbury, NY

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Please use a persistent id in citations: http://hdl.handle.net/2128/23675  doi:10.1103/PhysRevB.95.094111

Abstract: The dielectric function of several amorphous phase-change materials has been determined by employing a combination of impedance spectroscopy (9 kHz–3 GHz) and optical spectroscopy from the far- (20cm−1, 0.6 THz) to the near- (12000cm−1, 360 THz) infrared, i.e., from the DC limit to the first interband transition. While phase-change materials undergo a change from covalent bonding to resonant bonding on crystallization, the amorphous and crystalline phases of ordinary chalcogenide semiconductors are both governed by virtually the same covalent bonds. Here, we study the dielectric properties of amorphous phase-change materials on the pseudobinary line between GeTe and Sb2Te3. These data provide important insights into the charge transport and the nature of bonding in amorphous phase-change materials. No frequency dependence of permittivity and conductivity is discernible in the impedance spectroscopy measurements. Consequently, there are no dielectric relaxations. The frequency-independent conductivity is in line with charge transport via extended states. The static dielectric constant significantly exceeds the optical dielectric constant. This observation is corroborated by transmittance measurements in the far infrared, which show optical phonons. From the intensity of these phonon modes, a large Born effective charge is derived. Nevertheless, it is known that crystalline phase-change materials such as GeTe possess even significantly larger Born effective charges. Crystallization is hence accompanied by a huge increase in the Born effective charge, which reveals a significant change of bonding upon crystallization. In addition, a clear stoichiometry trend in the static dielectric constant along the pseudobinary line between GeTe and Sb2Te3 has been identified.

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Contributing Institute(s):

1. JARA Institut Green IT (PGI-10)

Research Program(s):

1. 521 - Controlling Electron Charge-Based Phenomena (POF3-521) (POF3-521)

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