Journal Article FZJ-2020-04535

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Quantum motion of hydrogen on Ni(100) surfaces



2020
Inst. Woodbury, NY

Physical review / B 102(16), 165405 () [10.1103/PhysRevB.102.165405]

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Abstract: Vibration modes of hydrogen atoms on Ni(100) are studied. The number of observed energy losses as well as their full width at half maximum (FWHM) are incompatible with the classical model of localized vibrations. Number and energy of modes agree, however, well with a previously published quantum-mechanical treatment of the motion of hydrogen in the periodic surface potential of Ni(100). For the dilute surface phase of hydrogen, the FWHM is a factor of 4 larger than expected from the dispersion of the bands. The effect is attributed to rapid tunneling of vibrationally excited hydrogen into empty neighboring sites.

Classification:

Contributing Institute(s):
  1. Elektronische Eigenschaften (PGI-6)
Research Program(s):
  1. 522 - Controlling Spin-Based Phenomena (POF3-522) (POF3-522)

Appears in the scientific report 2020
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Medline ; American Physical Society Transfer of Copyright Agreement ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Electronics and Telecommunications Collection ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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