Journal Article

FZJ-2021-00915

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Realizing high thermoelectric performance in n-type SnSe polycrystals via (Pb, Br) co-doping and multi-nanoprecipitates synergy

Gu, W.-H. ; Zhang, Y.FZJ* ; Guo, J. ; Cai, J.-F. ; Zhu, Y.-K. ; Zheng, F.FZJ* ; Jin, L. (Corresponding author)FZJ* ; Xu, J. ; Feng, J. ; Ge, Z.-H.

2021
Elsevier Lausanne

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Please use a persistent id in citations: http://hdl.handle.net/2128/27101  doi:10.1016/j.jallcom.2020.158401

Abstract: Both p- and n-type SnSe single crystals have been reported to possess high thermoelectric performances, thus highlighting the possibility for commercialization. Polycrystalline SnSe that has better mechanical properties however possesses inferior thermoelectric properties compared to single crystal SnSe. In this work, n-type polycrystalline SnSe0.95 + x wt% PbBr2 (x = 0, 0.5, 1, and 1.5) samples were synthesized by combining mechanical alloying and spark plasma sintering technology. The effects of PbBr2 doping on thermoelectric performance of SnSe were studied in detail. The results show that the carrier concentration was dramatically increased from 2.51 × 1017 cm−3 in pure SnSe0.95 to 1.79 × 1019 cm−3 in SnSe0.95 + 1.5 wt% PbBr2, further resulting in an enhanced electrical conductivity. Multi-nanoprecipitates are present in the samples, including SnO, SnPb and SnBrxOy, which possibly affect the Seebeck coefficient and the lattice thermal conductivity. A peak ZT value of 1.1 was obtained at 773 K for the SnSe0.95 + 1.0 wt% PbBr2 sample. This work highlights that PbBr2 is an effective dopant to improve the TE performance of n-type polycrystalline SnSe.

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Contributing Institute(s):

1. Physik Nanoskaliger Systeme (ER-C-1)

Research Program(s):

1. 535 - Materials Information Discovery (POF4-535) (POF4-535)

Appears in the scientific report 2021

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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