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Journal Article | FZJ-2021-01192 |
2021
Springer
Heidelberg
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Please use a persistent id in citations: http://hdl.handle.net/2128/28003 doi:10.1007/s00396-021-04825-6
Abstract: The random phase approximation for polymer blends was developed by H. Benoît and described small angle scattering functions as well as mean field phase boundaries. It is a pure mean field theory that loses validity close to the real phase boundaries due to strong fluctuations. However, it gives a very clear roadmap about phase diagrams and scattering functions. A simplification of the random phase approximation is discussed that comes into effect when several polymers are mixed that involve a rather low number of chemically different repeat units. Then, the correlation functions of the same repeat unit pairs can be added up in a specific way such that the overall complexity for the calculations is reduced. The scattering functions and mean field phase boundaries are discussed within this concept.
Keyword(s): Others (1st) ; Soft Condensed Matter (2nd)
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