Journal Article FZJ-2021-01706

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Micro-scale evolution of mechanical properties of glass-ceramic sealant for solid oxide fuel/electrolysis cells

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2021
Ceramurgia73399 Faenza

Ceramics international / Ci news 47(3), 3884 - 3891 () [10.1016/j.ceramint.2020.09.250]

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Abstract: The structural integrity of the sealant is critical for the reliability of solid oxide cells (SOCs) stacks. In this study, elastic modulus (E), hardness (H) and fracture toughness (KIC) of a rapid crystallizing glass of BaO–CaO–SiO2 system termed “sealant G” are reported as determined using an indentation test method at room temperature. A wide range of indentation loads (1 mN–10 N) was used to investigate the load-dependency of these mechanical properties. Values of 95 ± 12 GPa, 5.8 ± 0.2 GPa and 1.15 ± 0.07 MPa m0.5 were derived for E, H and KIC using the most suitable indentation loads. An application relevant annealing treatment of 500 h at 800 °C does not lead to a significant change of the mechanical properties. Potential self-healing behavior of the sealant has also been studied by electron microscopy, based on heat treatment of samples with indentation-induced cracks for 70 h at 850 °C. Although the sealant G is considered to be fully crystallized, evidence indicates that its cracks can be healed even in the absence of a dead load.

Classification:

Contributing Institute(s):
  1. Werkstoffstruktur und -eigenschaften (IEK-2)
  2. Zentralinstitut für Technologie (ZEA-1)
Research Program(s):
  1. 211 - Die Atmosphäre im globalen Wandel (POF4-211) (POF4-211)
  2. 122 - Elektrochemische Energiespeicherung (POF4-122) (POF4-122)

Appears in the scientific report 2021
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Medline ; Creative Commons Attribution-NonCommercial-NoDerivs CC BY-NC-ND 4.0 ; Embargoed OpenAccess ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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 Record created 2021-04-13, last modified 2025-07-01


Published on 2020-09-28. Available in OpenAccess from 2022-09-28.:
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