Journal Article

FZJ-2021-05565

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

Nimax, P. R. (Corresponding author) ; Rotthowe, N. ; Zoller, F.FZJ* ; Blockhaus, T. ; Wagner, F. ; Fattakhova, D.FZJ* ; Sünkel, K.

2021
Soc. London

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Please use a persistent id in citations: http://hdl.handle.net/2128/30080  doi:10.1039/D1DT02866A

Abstract: Compounds of the 5 amino (ATCC) and 5 nitro 1,2,3,4 tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy as well as UV-Vis spectroscopy. The investigation sheds light on the free radical activity in non- as well as transition metal compounds, and shows signs of photoinduced electron transfer in transition metal compounds of the ligands. We characterized silver(I) and potassium compounds of the compounds via X-ray diffraction, with one of the structures exhibiting a porous coordination polymer.

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Contributing Institute(s):

1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)

Research Program(s):

1. 1231 - Electrochemistry for Hydrogen (POF4-123) (POF4-123)

Appears in the scientific report 2021

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Database coverage:
; ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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