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Journal Article FZJ-2022-05302

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Hydrodynamic simulations of sedimenting dilute particle suspensions under repulsive DLVO interactions

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2022
Royal Soc. of Chemistry London

Soft matter 18(11), 2157 - 2167 () [10.1039/D1SM01294K]

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Abstract: We present guidelines to estimate the effect of electrostatic repulsion in sedimenting dilute particle suspensions. Our results are based on combined Langevin dynamics and lattice Boltzmann simulations for a range of particle radii, Debye lengths and particle concentrations. They show a simple relationship between the slope K of the sedimentation velocity over the concentration versus the range χ of the electrostatic repulsion normalized by the average particle-particle distance. When χ→0, the particles are too far away from each other to interact electrostatically and K=6.55 as predicted by the theory of Batchelor. As χ increases, K likewise increases up to a maximum around χ=0.5 and then decreases again to a concentration-dependent constant over the range χ=0.5−1, while the particles transition from a disordered gas-like distribution to a liquid-like state with a narrow distribution of the interparticle spacing.

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Contributing Institute(s):
  1. Helmholtz-Institut Erlangen-Nürnberg Erneuerbare Energien (IEK-11)
Research Program(s):
  1. 1215 - Simulations, Theory, Optics, and Analytics (STOA) (POF4-121) (POF4-121)
  2. DFG project 416229255 - SFB 1411: Produktgestaltung disperser Systeme (416229255)

Appears in the scientific report 2022
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Medline ; Creative Commons Attribution CC BY 3.0 ; OpenAccess ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Essential Science Indicators ; IF < 5 ; JCR ; National-Konsortium ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2022-11-29, last modified 2024-07-12


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