| Home > Workflow collections > Publication Charges > Hydrodynamic simulations of sedimenting dilute particle suspensions under repulsive DLVO interactions |
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| Journal Article | FZJ-2022-05302 |
; ; ; ; ;
2022
Royal Soc. of Chemistry
London
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Please use a persistent id in citations: http://hdl.handle.net/2128/33607 doi:10.1039/D1SM01294K
Abstract: We present guidelines to estimate the effect of electrostatic repulsion in sedimenting dilute particle suspensions. Our results are based on combined Langevin dynamics and lattice Boltzmann simulations for a range of particle radii, Debye lengths and particle concentrations. They show a simple relationship between the slope K of the sedimentation velocity over the concentration versus the range χ of the electrostatic repulsion normalized by the average particle-particle distance. When χ→0, the particles are too far away from each other to interact electrostatically and K=6.55 as predicted by the theory of Batchelor. As χ increases, K likewise increases up to a maximum around χ=0.5 and then decreases again to a concentration-dependent constant over the range χ=0.5−1, while the particles transition from a disordered gas-like distribution to a liquid-like state with a narrow distribution of the interparticle spacing.
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