Journal Article FZJ-2022-05633

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Towards the polymer nanocomposites based on hairy nanoparticles

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2022
Frontiers Media Lausanne

Frontiers in physics 10, 1041903 () [10.3389/fphy.2022.1041903]

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Abstract: Polymer nanocomposites exhibit versatility in their mechanical and structuralfeatures predominantly due to the huge surface area provided by nanoparticles.Interaction of the nanoparticles with polymer matrix selectively dictates theapplications suitable for a particular polymer nanocomposite system. Novelhybrid polymer-derived materials based on polymer grafted nanoparticles (NPs)can either be mixed with the polymer matrix or self-suspended without matrixpolymer. In both cases superior properties are demonstrated compared to thetraditional polymer nanocomposites, most notably by 1) incorporation of NPsinto polymers without “mixing problems” and 2) a wide range of the transportphenomena (from solids to viscous fluids). Hence, hairy nanoparticle-basednanocomposites are equipped to handle specific and unique challenges inmanufacturing and processing methods. It is known that the transportproperties can be tuned by altering the molecular design of hairynanoparticles (i.e., grafted polymer chemistry, NP concentrations, graftingdensity, and polymer molecular weight) and matrix polymer (e.g., molecularweight). In this article, we review the 1) most common methods of synthesizinghairy nanoparticle, 2) their microscopic dynamics and structural features and 3)some interesting applications of nanocomposite based on hairy nanoparticles.We discuss the effect of various parameters like nanoparticle size, molecularweight of the polymer etc. on the features of nanocomposites and itsimplications on the properties.

Classification:

Contributing Institute(s):
  1. Neutronenstreuung (JCNS-1)
  2. Neutronenstreuung und biologische Materie (IBI-8)
Research Program(s):
  1. 6G4 - Jülich Centre for Neutron Research (JCNS) (FZJ) (POF4-6G4) (POF4-6G4)
  2. 633 - Life Sciences – Building Blocks of Life: Structure and Function (POF4-633) (POF4-633)

Appears in the scientific report 2022
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Medline ; Creative Commons Attribution CC BY 4.0 ; DOAJ ; OpenAccess ; Article Processing Charges ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; DOAJ Seal ; Essential Science Indicators ; Fees ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection
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 Record created 2022-12-08, last modified 2024-06-19


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