Journal Article

FZJ-2022-05884

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Microstructural and mechanical characterization of Na1+xHf2Si2.3P0.7O10.85+0.5x and Na1+xZr2P3-xSixO12 NASICON-type solid electrolytes

Gross, J. P. (Corresponding author)FZJ* ; Dück, G.FZJ* ; Schäfer, F. ; Holzapfel, M. ; Finsterbusch, M.FZJ* ; Malzbender, J.FZJ* ; Schwaiger, R.FZJ*

2023
Springer Science + Business Media B.V Dordrecht [u.a.]

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Please use a persistent id in citations: http://hdl.handle.net/2128/33615  doi:10.1007/s10853-022-08023-9

Abstract: NASICON-type solid electrolytes are promising materials for novel solid-state-batteries aiming toward high energy densities. Na1+xHf2Si2.3P0.7O10.85+0.5x with varying sodium content as well as Sc- or Mg-doped and undoped Na1+xZr2P3-xSixO12 were synthesized by solution-assisted solid-state reaction. Microstructural and mechanical characteristics as well as conductivities were investigated. The electrochemical and microstructural properties of all studied materials appear to be highly affected by the sodium content glassy phase and secondary phase formation as well as bloating. The mechanical properties of the specimens depend mainly on microstructural characteristics. Our findings indicate improved mechanical behavior is achieved when bloating and secondary phase formation are inhibited. However, possible influences of glassy phase content on the material properties need to be further investigated.

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Contributing Institute(s):

1. Werkstoffstruktur und -eigenschaften (IEK-2)
2. Werkstoffsynthese und Herstellungsverfahren (IEK-1)

Research Program(s):

1. 1221 - Fundamentals and Materials (POF4-122) (POF4-122)

Appears in the scientific report 2023

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; Current Contents - Electronics and Telecommunications Collection ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; DEAL Springer ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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