Journal Article

FZJ-2015-02805

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Amorphous and highly nonstoichiometric titania (TiOx) thin films close to metal-like conductivity

Leichtweiss, T. ; Henning, R. A. ; Koettgen, J. ; Schmidt, R. M. ; Holländer, B.FZJ* ; Martin, M. ; Wuttig, M. ; Janek, J. (Corresponding Author)

2014
RSC London {[u.a.]

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Please use a persistent id in citations: http://hdl.handle.net/2128/8554  doi:10.1039/c3ta14816e

Abstract: Oxygen-deficient titanium oxide films (TiOx) have been prepared by pulsed laser deposition at room temperature. Samples in their as-deposited state have an average composition of TiO1.6, are optically absorbing and show electronic conductivities in the range of 10 S cm−1. The films are metastable and consist of grains of cubic titanium monoxide (γ-TiO) embedded in an amorphous TiO1.77 matrix. Upon annealing in an argon atmosphere the electrical conductivity of the films increases and comes close to metal-like conductivity (1000 S cm−1) at about 450 °C whereas the local structure is changed: nanocrystalline grains of metallic Ti are formed in the amorphous matrix due to an internal solid state disproportionation. The highly conductive state can be frozen by quenching. During heat treatment in an argon atmosphere a stoichiometric rutile TiO2 surface layer forms due to oxidation by residual oxygen. The combination of a highly conductive TiOx film with such an approximately 20 nm thick rutile cover layer leads to a surprisingly high efficiency for the water-splitting reaction without the application of an external potential.

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Contributing Institute(s):

1. Halbleiter-Nanoelektronik (PGI-9)
2. JARA-FIT (JARA-FIT)

Research Program(s):

1. 421 - Frontiers of charge based Electronics (POF2-421) (POF2-421)

Appears in the scientific report 2014

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Database coverage:
; ; ; Current Contents - Engineering, Computing and Technology ; Current Contents - Physical, Chemical and Earth Sciences ; IF < 5 ; JCR ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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