Journal Article

FZJ-2015-03306

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png An Ir IV -containing polyoxometalate

Adonin, S. A. ; Izarova, N. V. ; Besson, C.FZJ* ; Abramov, P. A. ; Santiago-Schübel, B.FZJ* ; Kögerler, P. (Corresponding Author)FZJ* ; Fedin, V. P. ; Sokolov, M. N.

2015
Soc. Cambridge

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Please use a persistent id in citations: http://hdl.handle.net/2128/22903  doi:10.1039/C4CC09271F

Abstract: [HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.

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Contributing Institute(s):

1. Analytik (ZEA-3)
2. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 899 - ohne Topic (POF3-899) (POF3-899)

Appears in the scientific report 2015

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Database coverage:
; ; ; Current Contents - Physical, Chemical and Earth Sciences ; IF >= 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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