Journal Article FZJ-2017-06569

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Chalcogenide-based van der Waals epitaxy: Interface conductivity of tellurium on Si(111)

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2017
Inst. Woodbury, NY

Physical review / B 96(3), 035301 () [10.1103/PhysRevB.96.035301]

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Abstract: We present a combined experimental and theoretical analysis of a Te rich interface layer which represents a template for chalcogenide-based van der Waals epitaxy on Si(111). On a clean Si(111)-(1×1) surface, we find Te to form a Te/Si(111)-(1×1) reconstruction to saturate the substrate bonds. A problem arising is that such an interface layer can potentially be highly conductive, undermining the applicability of the on-top grown films in electric devices. We perform here a detailed structural analysis of the pristine Te termination and present direct measurements of its electrical conductivity by in situ distance-dependent four-probe measurements. The experimental results are analyzed with respect to density functional theory calculations and the implications of the interface termination with respect to the electrical conductivity of chalcogenide-based topological insulator thin films are discussed. In detail, we find a Te/Si(111)-(1×1) interface conductivity of σTe2D=2.6(5)×10−7S/□, which is small compared to the typical conductivity of topological surface states.

Classification:

Contributing Institute(s):
  1. Funktionale Nanostrukturen an Oberflächen (PGI-3)
  2. Quanten-Theorie der Materialien (PGI-1)
  3. Halbleiter-Nanoelektronik (PGI-9)
  4. Physik Nanoskaliger Systeme (ER-C-1)
  5. Helmholtz - Nanofacility (HNF)
  6. Quanten-Theorie der Materialien (IAS-1)
  7. JARA-FIT (JARA-FIT)
  8. JARA - HPC (JARA-HPC)
Research Program(s):
  1. 521 - Controlling Electron Charge-Based Phenomena (POF3-521) (POF3-521)

Appears in the scientific report 2017
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Medline ; American Physical Society Transfer of Copyright Agreement ; OpenAccess ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection
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Document types > Articles > Journal Article
Institute Collections > ER-C > ER-C-1
JARA > JARA > JARA-JARA\-FIT
JARA > JARA > JARA-JARA\-HPC
Institute Collections > IAS > IAS-1
Institute Collections > PGI > PGI-3
Institute Collections > PGI > PGI-1
Institute Collections > PGI > PGI-9
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 Record created 2017-09-14, last modified 2023-04-26