Journal Article

FZJ-2020-05108

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png Phthalocyanine-polyoxotungstate lanthanide double deckers

Sarwar, S.FZJ* ; Sanz, S. ; van Leusen, J. ; Nichol, G. S. ; Brechin, E. K. ; Kögerler, P. (Corresponding author)FZJ*

2020
Soc. London

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Please use a persistent id in citations: http://hdl.handle.net/2128/26792  doi:10.1039/D0DT03716H

Abstract: Acetate ligand metathesis results in the first hybrid [MIII(Pc)(PW11O39)]6− (M = Y, Dy, Tb) double-decker scaffolds, where a phthalocyanate (Pc2−) and one of the conceptually most simple polyoxotungstates, a monolacunary Keggin cluster, are interlinked via a single rare earth ion. Characterisation includes high-resolution mass spectrometry, synchrotron-based single-crystal X-ray diffraction, various spectroscopic and electrochemical methods, and magnetic studies revealing slow relaxation of the magnetisation for the Dy derivate.

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Contributing Institute(s):

1. Elektronische Eigenschaften (PGI-6)

Research Program(s):

1. 522 - Controlling Spin-Based Phenomena (POF3-522) (POF3-522)

Appears in the scientific report 2020

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Database coverage:
; ; Allianz-Lizenz / DFG ; Chemical Reactions ; Clarivate Analytics Master Journal List ; Current Contents - Physical, Chemical and Earth Sciences ; Ebsco Academic Search ; Essential Science Indicators ; IF < 5 ; JCR ; National-Konsortium ; Nationallizenz ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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