Journal Article

FZJ-2021-04032

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png The influence of hafnium impurities on the electrochemical performance of tantalum substituted Li7La3Zr2O12 solid electrolytes

Mann, M.FZJ* ; Küpers, M.FZJ* ; Häuschen, G.FZJ* ; Finsterbusch, M. (Corresponding author)FZJ* ; Fattakhova-Rohlfing, D.FZJ* ; Guillon, O.FZJ*

2021
Springer Heidelberg

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Please use a persistent id in citations: http://hdl.handle.net/2128/30254  doi:10.1007/s11581-021-04300-w

Abstract: Garnet-based Li7La3Zr2O12 (LLZO) is considered one of the most promising oxide-ceramic solid electrolyte materials for inorganic all-solid-state batteries. Dopants and substituents like Al, Ta, Nb, Ga, and W were shown to have a high impact on the total ionic conductivity, increasing it from 10−6 S/cm up to 10−3 S/cm. However, natural zirconium sources always contain a small amount of hafnium which could also act as dopant, but the separation of these two elements is complicated and expensive. In this work, we investigate the influence of various Hf-impurity concentrations on the performance of tan-talum-doped LLZO. We synthesised Li6.45Al0.05La3Zr1.6−xHfxTa0.4O12 (LLZHO with x = 0 – 1.6) via conventional solid-state synthesis and have demonstrated that up to x = 0.1, hafnium impurities do not have a significant impact on the performance of the material. Above this concentration, the Li-ion conductivity is steadily reduced to around 70% when zirconium is fully substituted by hafnium resulting in Li6.45Al0.05La3Hf1.6Ta0.4O12. As the purity of Zr precursors has a great impact on their price, these findings can help to reduce the price of LLZO in general, as lower grade zirconium can be used in industrial scale applications.

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Contributing Institute(s):

1. Werkstoffsynthese und Herstellungsverfahren (IEK-1)

Research Program(s):

1. 1222 - Components and Cells (POF4-122) (POF4-122)
2. LISZUBA - Lithium-Schwefel-Feststoffbatterien als Zukunftsbatterie (03XP0115B) (03XP0115B)
3. FestBatt-Oxide - Materialplattform 'Oxide' im Rahmen des Kompetenzclusters für Festkörperbatterien (13XP0173A) (13XP0173A)

Appears in the scientific report 2021

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Database coverage:
; ; ; Clarivate Analytics Master Journal List ; DEAL Springer ; Essential Science Indicators ; IF < 5 ; JCR ; SCOPUS ; Science Citation Index Expanded ; Web of Science Core Collection

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