Journal Article

FZJ-2015-07130

http://join2-wiki.gsi.de/foswiki/pub/Main/Artwork/join2_logo100x88.png In situ determination of surface relaxivities for unconsolidated sediments

Duschl, M.FZJ* ; Galvosas, P. (Corresponding author) ; Brox, T. I. ; Pohlmeier, A.FZJ* ; Vereecken, H.FZJ*

2015
AGU Washington, DC

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Please use a persistent id in citations: http://hdl.handle.net/2128/17087  doi:10.1002/2014WR016574

Abstract: NMR relaxometry has developed into a method for rapid pore-size determination of natural porous media. Nevertheless, it is prone to uncertainties because of unknown surface relaxivities which depend mainly on the chemical composition of the pore walls as well as on the interfacial dynamics of the pore fluid. The classical approach for the determination of surface relaxivities is the scaling of NMR relaxation times by surface to volume ratios measured by gas adsorption or mercury intrusion. However, it is preferable that a method for the determination of average pore sizes uses the same substance, water, as probe molecule for both relaxometry and surface to volume measurements. One should also ensure that in both experiments the dynamics of the probe molecule takes place on similar length scales, which are in the order of some microns. Therefore, we employed NMR diffusion measurements with different observation times using bipolar pulsed field gradients and applied them to unconsolidated sediments (two purified sands, two natural sands, and one soil). The evaluation by Mitra's short-time model for diffusion in restricted environments yielded information about the surface to volume ratios which is independent of relaxation mechanisms. We point out that methods based on NMR diffusometry yield pore dimensions and surface relaxivities consistent with a pore space as sampled by native pore fluids via the diffusion process. This opens a way to calibrate NMR relaxation measurements with other NMR techniques, providing information about the pore-size distribution of natural porous media directly from relaxometry.

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Contributing Institute(s):

1. Agrosphäre (IBG-3)

Research Program(s):

1. 255 - Terrestrial Systems: From Observation to Prediction (POF3-255) (POF3-255)

Appears in the scientific report 2015

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Database coverage:
; ; Current Contents - Agriculture, Biology and Environmental Sciences ; Current Contents - Engineering, Computing and Technology ; IF < 5 ; JCR ; NCBI Molecular Biology Database ; SCOPUS ; Science Citation Index ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection

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