Journal Article FZJ-2014-02831

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Optical and Electrical Effects of p-type μc-SiOx:H in Thin-Film Silicon Solar Cells on Various Front Textures

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2014
Hindawi Publ. Corp. New York, NY [u.a.]

International journal of photoenergy 2014, 1 - 10 () [10.1155/2014/176965]

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Abstract: p-type hydrogenated microcrystalline silicon oxide (µc-Si :H) was developed and implemented as a contact layer in hydrogenated amorphous silicon (a-Si:H) single junction solar cells. Higher transparency, sufficient electrical conductivity, low ohmic contact to sputtered ZnO:Al, and tunable refractive index make p-type µc-Si :H a promising alternative to the commonly used p-type hydrogenated microcrystalline silicon (µc-Si:H) contact layers. In this work, p-type µc-Si :H layers were fabricated with a conductivity of up to 10−2 S/cm and a Raman crystallinity of above 60%. Furthermore, we present p-type µc-Si :H films with a broad range of optical properties (2.1 eV < band gap  eV and 1.6 < refractive index ). These properties can be tuned by adapting deposition parameters, for example, the CO2/SiH4 deposition gas ratio. A conversion efficiency improvement of a-Si:H solar cells is achieved by applying p-type µc-Si :H contact layer compared to the standard p-type µc-Si:H contact layer. As another aspect, the influence of the front side texture on a-Si:H p-i-n solar cells with different p-type contact layers, µc-Si:H and µc-Si :H, is investigated. Furthermore, we discuss the correlation between the decrease of and the cell surface area derived from AFM measurements.

Classification:

Contributing Institute(s):
  1. Photovoltaik (IEK-5)
Research Program(s):
  1. 111 - Thin Film Photovoltaics (POF2-111) (POF2-111)
  2. HITEC - Helmholtz Interdisciplinary Doctoral Training in Energy and Climate Research (HITEC) (HITEC-20170406) (HITEC-20170406)

Appears in the scientific report 2014
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Creative Commons Attribution CC BY 3.0 ; DOAJ ; OpenAccess ; JCR ; SCOPUS ; Science Citation Index Expanded ; Thomson Reuters Master Journal List ; Web of Science Core Collection ; Zoological Record
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 Record created 2014-04-15, last modified 2024-07-12


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